Directed heterodimerization: stereocontrolled assembly via solvent-caged unsymmetrical diazene fragmentation.
نویسندگان
چکیده
A general strategy for the directed and stereocontrolled assembly of carbon-carbon linked heterodimeric hexahydropyrroloindoles is described. The stepwise union of complex amines in the form of mixed diazenes followed by photoexpulsion of dinitrogen in a solvent cage provides completely guided assembly at challenging C(sp(3))-C(sp(3)) and C(sp(3))-C(sp(2)) connections.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 133 33 شماره
صفحات -
تاریخ انتشار 2011